Applying Charles's Law: Understanding Gas Behavior

how to apply charles law

Charles's Law, also known as the Law of Volumes, is an experimental gas law formulated by French physicist Jacques Charles in the 1780s. The law describes the relationship between the volume and temperature of a gas at constant pressure. In simple terms, it states that as the temperature of a gas increases, its volume increases, and conversely, as the temperature decreases, its volume decreases. This law has various practical applications in everyday life, such as understanding the behaviour of hot air balloons, car tyres, and even a simple helium balloon.

Characteristics Values
What is Charles' Law? An experimental gas law that describes how gases expand when heated.
When does it apply? When the pressure on a sample of dry gas is held constant.
What is the relationship between volume and temperature? Directly proportional.
What is the relationship between volume and temperature when comparing the same substance under two different conditions? V1/T1 = V2/T2
What is the relationship between volume and temperature when the pressure is constant? V = kT
What is the relationship between volume and temperature when the temperature is absolute? V ∝ T
What is the relationship between volume and temperature when the temperature is not absolute? V1T2 = V2T1
What is the effect of temperature on volume? Doubling the temperature of a gas doubles its volume. Halving the temperature of a gas halves its volume.
What is the effect of temperature on pressure? If the gas container is inflexible, the more frequent and forceful collisions of molecules will result in increased pressure.
What is the effect of temperature on density? Decreasing the temperature of a gas increases its density.

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Hot air balloons rise due to decreased density

Jacques Charles, a French physicist, discovered in the 1780s that heating a gas will cause it to expand. Charles' Law, also known as the law of volumes, states that the volume of a gas is directly proportional to its temperature when pressure is held constant.

This principle is evident in the functioning of hot air balloons. When the air inside the balloon is heated, it expands, and the hot air inside becomes less dense than the surrounding air. This is because the molecules move faster and disperse within the space, causing the gas to take up more volume. As a result, the balloon rises due to its decreased density, allowing it to float.

The application of Charles' Law in hot air balloons can be observed when a torch is used to heat the air molecules inside the balloon. The molecules move faster and occupy more space, leading to a decrease in density. The volume of the balloon remains constant, but there is a hole at the bottom for the extra volume of air to escape. As the density of the balloon decreases, it becomes less than the density of the outside air, and the balloon rises.

This phenomenon can be explained by Archimedes' Principle, which states that an object will float if it weighs less than the fluid it displaces. When the air inside the balloon is heated, the net weight of the balloon and hot air is less than the weight of the same volume of cold air, causing the balloon to rise. Conversely, when the gas in the balloon cools, the volume of hot air decreases, cold air moves in through the hole, and the balloon starts to sink as its weight increases.

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Helium balloons shrink in cold weather

Helium balloons shrinking in cold weather is a classic example of Charles's Law in action. This law, formulated by French physicist Jacques Charles in the 1780s, states that the volume of a gas is directly proportional to its temperature when pressure is held constant. In other words, as the temperature of a gas increases, so does its volume, and conversely, when the temperature decreases, the volume decreases.

Now, let's apply this law to helium balloons in cold weather:

How Helium Balloons Shrink in Cold Weather:

  • Temperature Decrease: When a helium balloon is taken outside on a cold day, the temperature of the helium gas inside it decreases. Charles's Law tells us that as the temperature of the gas goes down, its volume will also decrease. This is because the gas molecules slow down and become less energetic, taking up less space.
  • Volume Decrease: As the temperature of the helium gas drops, the volume of the gas inside the balloon decreases. The balloon appears to shrink as the gas takes up less space. This happens because the kinetic energy of the gas molecules decreases, causing them to move more slowly and occupy a smaller volume.
  • Pressure and Density: While the temperature decrease leads to a smaller volume, it also affects pressure and density. The pressure inside the balloon decreases as the temperature drops. At the same time, the density of the helium gas increases because the molecules are closer together. This increase in density is why the helium becomes denser than the surrounding air, contributing to the balloon's shrinking appearance.
  • Temporary Effect: It's important to note that the balloon isn't actually deflating; the gas is just taking up less space due to the lower temperature. When the balloon is brought back into a warmer environment, the temperature of the helium gas increases, and the balloon returns to its original shape as the gas expands.

Everyday Examples of Charles's Law:

The phenomenon observed in helium balloons during cold weather is not an isolated event. Charles's Law is applicable in various everyday situations, including:

  • The bursting of a deodorant bottle left in direct sunlight. The high temperatures cause the gas molecules inside to expand, leading to the bottle bursting.
  • The opening of a warm soda can. The higher temperature inside the can causes the gas volume to increase, resulting in bubbles spilling out.
  • The working of a hot air balloon. As the air inside the envelope is heated, its volume increases, making the air less dense than the surrounding atmosphere, and causing the balloon to rise.
  • Baking bread and cakes. The use of yeast produces carbon dioxide gas, which expands during baking, resulting in soft and fluffy baked goods.

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Tyre pressure changes with temperature

Charles's Law, also known as the law of volumes, states that the volume of an ideal gas is directly proportional to its temperature in Kelvin, provided the pressure and the amount of gas remain constant. This law was formulated in the 1780s by French physicist Jacques Charles, although it was not published until the early 1800s by Gay-Lussac, who credited Charles.

Charles's Law can be applied to understand tyre pressure changes with temperature. The pressure in a tyre is directly proportional to the temperature of the gas inside it. So, if the amount of air in a tyre remains constant, a drop in temperature will lead to a decrease in tyre pressure, and vice versa. For example, if a tyre has 35 PSI (Pounds per Square Inch) at 20°C, and the temperature drops to 0°C, the tyre pressure will decrease. This can cause warning lights to come on, indicating low tyre pressure.

To avoid this issue, it is recommended to test tyre pressure when the tyres are cold and to use a reliable pressure gauge. Additionally, it is important to regularly monitor tyre pressure and ensure that under-inflated tyres are properly inflated. Under-inflated tyres can negatively affect traction and fuel economy.

Charles's Law also has other real-world applications, such as explaining why helium balloons shrink in cold weather and why it becomes more difficult to perform athletic activities in cold environments.

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Using a turkey timer

A pop-up turkey timer is a great example of Charles's Law in action. This law, formulated by French scientist Jacques Charles in the 1780s, states that the volume of a gas is directly proportional to its temperature when pressure is held constant.

The pop-up turkey timer is placed inside the turkey as it cooks. As the temperature rises, the gas inside the thermometer expands. This is due to the molecules within the gas moving more quickly and colliding with more force and frequency, as described by Charles's Law. This expansion of gas is what makes the timer pop up, indicating that the turkey is cooked and ready to serve.

The thermometer is carefully calibrated so that the cap pops off at the correct internal temperature, ensuring the turkey is cooked perfectly. This is a practical application of Charles's Law, which can be used to understand the behaviour of gases in everyday situations.

It is worth noting that Charles's Law is one of the three special cases of the Ideal Gas Law, alongside Boyle's Law and Gay-Lussac's Law. Charles's Law describes the relationship between volume and temperature, while Boyle's Law relates to the link between pressure and volume, and Gay-Lussac's Law concerns constant volume.

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Fixing a dented ping pong ball

To fix a dented ping pong ball, simply follow these steps:

Step 1:

Boil a glass of water in a kettle or pot. Pour the hot water into a ceramic cup and drop the dented ping pong ball into it. Ensure that the water is at a high temperature.

Step 2:

You can use a spoon to push the ball down into the hot water and leave it submerged for 15-20 seconds. This step is important to ensure that the air inside the ball heats up sufficiently.

Step 3:

Carefully remove the ball from the hot water using a spoon or fork. Do not handle the ball with your bare hands as it will be very hot.

Step 4:

Wrap a dry tissue or handkerchief around the ball and let it cool down for 5-10 minutes. Do not place the hot ball directly on a flat surface as this may cause it to deform.

As the ball and the air inside it cool down, the air molecules will slow down and the volume of the air will decrease, causing the ball to deflate slightly. This process of heating and cooling the air inside the ball allows it to regain its original shape and fixes the dent.

You can also use a hairdryer or hold the ball over a flame to heat the air inside it, but these methods may be more difficult to control and could potentially damage the ball if not done carefully.

Frequently asked questions

Charles's Law, or the law of volumes, is an experimental gas law formulated by French scientist Jacques Charles in the 1780s. It describes the relationship between the volume and temperature of a gas at constant pressure. The law states that the volume of a gas is directly proportional to its temperature, i.e., as temperature increases, so does volume, and vice versa.

Charles's Law can be applied using the formula: V1/T1 = V2/T2, where V is volume and T is absolute temperature in Kelvin. For example, if you have a gas with a volume of 221 cm3 at 0°C and want to find its volume at 100°C, you would convert the temperatures to Kelvin (0°C = 273K, 100°C = 373K), then plug the values into the equation: V1/T1 = V2/T2, 221cm3 / 273K = V2 / 373K, yielding V2 = 302 cm3.

Charles's Law has numerous real-life applications. For example, hot air balloons operate based on this principle: heating the air inside the balloon increases its volume, reducing its density, and causing it to rise. Similarly, pop-up turkey thermometers work by utilising the expansion of air inside the thermometer as the turkey cooks. Car tyre pressure changes due to temperature variations are also explained by Charles's Law.

Charles's Law calculations require the use of an absolute temperature scale, such as Kelvin. This is because relative scales like Celsius or Fahrenheit can lead to impossible negative volume calculations and do not accurately represent the scaling of energy. The Kelvin scale ensures accurate and meaningful results when dealing with the relationship between volume and temperature in gases.

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